Hydrogen bonding promoted simple and clean photo-induced reduction of C–X bond with isopropanol

Author:

Cao Dawei12345,Yan Chaoxian5234,Zhou Panpan5234ORCID,Zeng Huiying12345ORCID,Li Chao-Jun12346ORCID

Affiliation:

1. The State Key Laboratory of Applied Organic Chemistry

2. Lanzhou University

3. Lanzhou

4. P. R. China

5. College of Chemistry and Chemical Engineering

6. Department of Chemistry and FQRNT Centre for Green Chemistry and Catalysis

Abstract

We herein report a simple and clean photo-induced metal-free reduction of C–X bond under an atmosphere of air at room temperature.

Funder

Fonds Québécois de la Recherche sur la Nature et les Technologies

Canada Foundation for Innovation

Canada Research Chairs

Natural Sciences and Engineering Research Council of Canada

Gansu Science and Technology Department

Recruitment Program of Global Experts

Lanzhou University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference35 articles.

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2. J. D. Nguyen , E. M.D’Amato and C. R. J.Stephenson , Reduction of Alkenyl Halides to Alkenes, and of Aryl Halides and Related Compounds to Arenes , in Comprehensive Organic Synthesis , ed. G. A. Molander and P. Knochel , Elsevier , Oxford , 2nd edn, 2014 , vol. 8, pp. 1123–1142

3. Dehalogenation of polychlorinated biphenyls and polybrominated diphenyl ethers using a hybrid bioinorganic catalyst

4. Reduction of Organic Compounds by Organotin Hydrides

5. Rate constants and Arrhenius parameters for the reactions of primary, secondary, and tertiary alkyl radicals with tri-n-butyltin hydride

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