Intermolecular C–C/C–N σ-bond metathesis enabled by visible light-Reference-Cited by-同舟云学术

Intermolecular C–C/C–N σ-bond metathesis enabled by visible light

Published:2024 Issue:32 Volume:15 Page:12900-12905
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Rujuan¹,Zhan Renqin¹,Lang Yatao¹,Li Chao-Jun²^ORCID,Zeng Huiying¹^ORCID

Affiliation:

1. The State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui Road, Lanzhou, 730000, P. R. China

2. Department of Chemistry, and FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke St. West, Montreal, QC H3A 0B8, Canada

Abstract

We present a novel photo-induced approach that does not rely on transition metals or photosensitizers to drive C–C and C–N σ-bond metathesis reactions. This method enables the cross-coupling of tertiary amines with α-diketones.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

International Joint Research Center for Green Catalysis and Synthesis

E.B. Eddy Endowment Fund

Science and Technology Program of Gansu Province

Canada Research Chairs

Canada Foundation for Innovation

Natural Sciences and Engineering Research Council of Canada

Fonds Québécois de la Recherche sur la Nature et les Technologies

Publisher

Royal Society of Chemistry (RSC)