Acenaphthoimidazolium chloride-enabled nickel-catalyzed amination of bulky aryl tosylates

Author:

Jiang Jian123,Zhu Haibo123,Shen Yajing123,Tu Tao123

Affiliation:

1. Department of Chemistry

2. Fudan University

3. Shanghai, China

Abstract

A robust catalyst derived from NiCl2·(DME) and acenaphthoimidazolium chloride exhibited high activity towards the challenging amination of bulky and heterocyclic aryl tosylates with secondary and primary amines under mild reaction conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference51 articles.

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3. Nucleophilic Displacements of Activated Fluorine in Aromatic Compounds

4. Nucleophilic aromatic substitution reactions of unactivated aryl chlorides with methoxide ion in hexamethylphosphoramide

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