Complexation of uranium(vi) with glutarimidoxioxime: thermodynamic and computational studies-Reference-Cited by-同舟云学术

Complexation of uranium(vi) with glutarimidoxioxime: thermodynamic and computational studies

Published:2015 Issue:31 Volume:44 Page:13835-13844
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Endrizzi Francesco¹²³⁴,Melchior Andrea⁵⁶⁷⁸,Tolazzi Marilena⁵⁶⁷⁸,Rao Linfeng¹²³⁴

Affiliation:

1. Chemical Sciences Division

2. Lawrence Berkeley National Laboratory

3. Berkeley

4. USA

5. Dipartimento Chimica Fisica e Ambiente

6. Università di Udine

7. 33100 Udine

8. Italy

Abstract

Glutarimidoxioxime forms a bidentate complex with UO₂²⁺via the oxime and imino groups. Hydrogen bonding between water and the carbonyl group helps to stabilize the complex. The complex is much weaker than that of glutarimidedioxime previously studied.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00261C

Reference39 articles.

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4. Chemical Speciation of Uranium(VI) in Marine Environments: Complexation of Calcium and Magnesium Ions with [(UO2)(CO3)3]4−and the Effect on the Extraction of Uranium from Seawater

5. Formation of ternary CaUO2(CO3)32− and Ca2UO2(CO3)3(aq) complexes under neutral to weakly alkaline conditions

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