Combination of fluoroalkylation and Kornblum–DeLaMare reaction: a new strategy for the construction of (Z)-β-perfluoroalkyl enaminones-Reference-Cited by-同舟云学术

Combination of fluoroalkylation and Kornblum–DeLaMare reaction: a new strategy for the construction of (Z)-β-perfluoroalkyl enaminones

Published:2015 Issue:7 Volume:51 Page:1214-1217
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liu Chunmei¹²³⁴⁵,Shi Erbo¹²³⁴⁵,Xu Feng⁶⁷⁸,Luo Qiang¹²³⁴⁵,Wang Hongxiang¹²³⁴⁵,Chen Jijun¹²³⁴⁵,Wan Xiaobing¹²³⁴⁵

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province

2. College of Chemistry

3. Chemical Engineering and Materials Science

4. Soochow University

5. 215123 Suzhou

6. SABIC Technology Center

7. Riyadh 11551

8. Saudi Arabia

Abstract

A novel strategy has been developed for the highly chemo- and stereo-selective synthesis of (Z)-β-perfluoroalkyl enaminones via a multicomponent radical reaction involving sequential fluoroalkylation and Kornblum–DeLaMare reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C4CC07833K

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