A thermodynamic insight into the recognition of hydrophilic and hydrophobic amino acids in pure water by aza-scorpiand type receptors

Author:

Blasco Salvador123,Verdejo Begoña123,Bazzicalupi Carla456,Bianchi Antonio456,Giorgi Claudia456,Soriano Concepción123,García-España Enrique123

Affiliation:

1. Instituto de Ciencia Molecular

2. 46980 Paterna

3. Spain

4. Dipartimento di Chimica

5. 50019 Sesto Fiorentino

6. Italy

Abstract

Thermodynamic studies about the interaction of scorpiand aza-macrocycles with amino acids in water show entropy driven stabilisations often associated with solvation/desolvation processes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference35 articles.

1. J.-M. Lehn , Supramolecular Chemistry. Concepts and Perspectives, Wiley-VCH, Weinheim, 1995

2. Anion Coordination Chemistry, ed. K. Bowman-James, A. Bianchi and E. García-España, Wiley-VCH, Verlag GmbH & Co., Weinheim, Germany, 2012

3. J. W. Steed and J. L.Atwood, Supramolecular Chemistry, Wiley-VCH, 2nd edn, 2009

4. J. L. Sessler , P. A.Gale and W. S.Cho, Anion Receptor Chemistry, Royal Society of Chemistry, Cambridge, 2006

5. Supramolecular Chemistry of Anions, ed. A. Bianchi, K. Bowman-James and E. García-España, Wiley-VCH Verlag, GmbH, New York, 1997

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