Stabilization of polyiodide networks with Cu(ii) complexes of small methylated polyazacyclophanes: shifting directional control from H-bonds to I⋯I interactions
Author:
Affiliation:
1. ICMol
2. Department of Inorganic Chemistry
3. University of Valencia
4. Paterna
5. Spain
6. Department of Chemistry “Ugo Schiff”
7. University of Florence
8. 50019 Sesto Fiorentino
9. Italy
10. Department of Organic Chemistry
Abstract
Modulation of hydrogen bonds and iodine–iodine interactions, both covalent and supramolecular, unlocks novel possibilities for the construction of transition metal-polyiodide hybrid networks.
Funder
Ministerio de Economía y Competitividad
European Regional Development Fund
European Cooperation in Science and Technology
Ministerio de Ciencia, Innovación y Universidades
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QI/D0QI00912A
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3. A thermodynamic insight into the recognition of hydrophilic and hydrophobic amino acids in pure water by aza-scorpiand type receptors
4. Significant In Vivo Anti-Inflammatory Activity of Pytren4Q-Mn a Superoxide Dismutase 2 (SOD2) Mimetic Scorpiand-Like Mn (II) Complex
5. Mn(II) complexes of scorpiand-like ligands. A model for the MnSOD active centre with high in vitro and in vivo activity
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