Transition metal-promoted biomimetic steps in total syntheses-Reference-Cited by-同舟云学术

Transition metal-promoted biomimetic steps in total syntheses

Published:2014 Issue:4 Volume:31 Page:533-549
ISSN:0265-0568
Container-title:Nat. Prod. Rep.
language:en
Short-container-title:Nat. Prod. Rep.

Author:

Li Xu-Wen¹²³,Nay Bastien¹²³

Affiliation:

1. Muséum National d'Histoire Naturelle and Centre National de la Recherche Scientifique

2. Unité “Molécules de Communication et Adaptation des Micro-organismes” (UMR 7245 CNRS-MNHN)

3. 75005 Paris, France

Abstract

Important biomimetic steps in natural product synthesis have been promoted by transition metals, as exemplified by this beautiful ruthenium-catalyzed rearrangement of an endoperoxide into elysiapyrone A. Such reactions are supposed to occur during the biosynthesis, yet under different catalysis conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/NP/C3NP70077A

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