Stereoselectivity and nonmigratory insertion mechanism of dimethylacetylene dicarboxylate into metallocene‐hydride of Cp 2 M(L)H [Cp = η 5 ‐C 5 H 5 ; M = Nb, V; L = CO, P (OMe) 3 ]: A DFT study-Reference-Cited by-同舟云学术

Stereoselectivity and nonmigratory insertion mechanism of dimethylacetylene dicarboxylate into metallocene‐hydride of Cp 2 M(L)H [Cp = η 5 ‐C 5 H 5 ; M = Nb, V; L = CO, P (OMe) 3 ]: A DFT study

Published:2020-05 Issue:5 Volume:34 Page:
ISSN:0268-2605
Container-title:Applied Organometallic Chemistry
language:en
Short-container-title:Appl Organometal Chem

Author:

Huo Suhong¹²,Li Xiaoyan³^ORCID,Zeng Yanli³,Meng Lingpeng¹^ORCID

Affiliation:

1. College of Physics Science and Information EngineeringHebei Normal University Shijiazhuang 050024 P. R. China

2. Engineering collegeYanching Institute of Technology Langfang 065201 P. R. China

3. College of Chemistry and Material ScienceHebei Normal University Shijiazhuang 050024 P. R. China

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hebei Province

Publisher

Wiley

Subject

Inorganic Chemistry,General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/aoc.5601

Reference57 articles.

1. Alkyl Alkyne Mono((trimethylsilyl)cyclopentadienyl) Niobium Complexes. Synthesis and Chemical Behavior in Insertion Processes. X-ray Crystal Structures of [NbCp‘(CH2SiMe3)2(Me3SiCCSiMe3)] and [NbCp‘(NAr){η4-CH(SiMe3)C(SiMe3)C(CH2SiMe3)CH(SiMe3)}], (Cp‘ = η5-C5H4SiMe3, Ar = 2,6-Me2C6H3). DFT Studies of the Model Complexes [Nb(η5-C5H5)R2(HCCH)] (R = Cl, Me)

2. Hydride Transfer from (η5-C5Me5)(CO)2MH (M = Fe, Ru, Os) to Trityl Cation: Different Products from Different Metals and the Kinetics of Hydride Transfer

3. Thermodynamic Hydricity of Transition Metal Hydrides

4. Z−H Bond Activation in (Di)hydrogen Bonding as a Way to Proton/Hydride Transfer and H2 Evolution

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3. Substituent-regulated mechanism on reaction Cp2NbH3 (Cp = η5-C5H5) with RCCR (R = COOMe and Me);Dalton Transactions;2020