Alkyl Alkyne Mono((trimethylsilyl)cyclopentadienyl) Niobium Complexes. Synthesis and Chemical Behavior in Insertion Processes. X-ray Crystal Structures of [NbCp‘(CH2SiMe3)2(Me3SiCCSiMe3)] and [NbCp‘(NAr){η4-CH(SiMe3)C(SiMe3)C(CH2SiMe3)CH(SiMe3)}], (Cp‘ = η5-C5H4SiMe3, Ar = 2,6-Me2C6H3). DFT Studies of the Model Complexes [Nb(η5-C5H5)R2(HCCH)] (R = Cl, Me)-Reference-Cited by-同舟云学术

Alkyl Alkyne Mono((trimethylsilyl)cyclopentadienyl) Niobium Complexes. Synthesis and Chemical Behavior in Insertion Processes. X-ray Crystal Structures of [NbCp‘(CH2SiMe3)2(Me3SiCCSiMe3)] and [NbCp‘(NAr){η4-CH(SiMe3)C(SiMe3)C(CH2SiMe3)CH(SiMe3)}], (Cp‘ = η5-C5H4SiMe3, Ar = 2,6-Me2C6H3). DFT Studies of the Model Complexes [Nb(η5-C5H5)R2(HCCH)] (R = Cl, Me)

Published:2001-12-15 Issue:2 Volume:21 Page:293-304
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Galindo Agustín¹,Gómez Manuel¹,Gómez-Sal Pilar¹,Martín Avelino¹,del Río Diego¹,Sánchez Fernando¹

Affiliation:

1. Departamento de Química Inorgánica, Universidad de Alcalá de Henares, Campus Universitario, E-28871 Alcalá de Henares, Spain, and Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo. 553, E-41071 Sevilla, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om010521a

Reference126 articles.

1. Metal-promoted carbon-carbon bond formation from one-carbon functional groups: modeling study for reductive coupling of carbon dioxide

2. Structural eludication of some new titanacycles by means of degradation and 13C NMR studies

3. Carbon-carbon bond formation by reductive coupling of two carbonyl ligands of binuclear transition metal complexes

4. Preparation and reaction of metal-ketene complexes of zirconium and titanium

5. η2benzophenonzirconocen, ein modell für das reaktionsverhalten eines metallaoxirans?

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