Hidden ordered structure in the archetypical Fe(pyrazine)[Pt(CN)<sub>4</sub>] spin-crossover porous coordination compound-Reference-Cited by-同舟云学术

Hidden ordered structure in the archetypical Fe(pyrazine)[Pt(CN)₄] spin-crossover porous coordination compound

Published:2022 Issue:36 Volume:24 Page:6349-6356
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Fernández-Blanco Ángel¹²,Mariano Lorenzo A.²,Piñeiro-López Lucía³,Real José Antonio⁴^ORCID,Costa Jose Sanchez³^ORCID,Poloni Roberta²^ORCID,Rodríguez-Velamazán J. Alberto¹^ORCID

Affiliation:

1. Institut Laue Langevin, 71 Avenue des Martyrs, CS 20156-38042, Grenoble, France

2. Univ. Grenoble Alpes, SIMaP, Grenoble-INP, CNRS, F-38042, Grenoble, France

3. IMDEA Nanociencia, Faraday 9, Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain

4. Departamento de Química Inorgánica, Insituto de Ciencia Molecular (ICMol), Universidad de Valencia, 46980, Paterna, Spain

Abstract

The actual low-spin state of Fe(pyrazine)Pt(CN)4 implies an ordered arrangement of the pyrazine rings, which significantly affects the spin transition.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CE/D2CE00895E

Reference54 articles.

1. P.Gütlich and H. A.Goodwin , Spin-Crossover in Transition Metal Compounds, in Topics in Current Chemistry , Springer , Berlin , 2004 , vol. I–III

2. Spin Crossover in a Catenane Supramolecular System

3. A spin transition mechanism for cooperative adsorption in metal–organic frameworks