The first example of ab initio calculations of f–f transitions for the case of [Eu(DOTP)]5− complex—experiment versus theory-Reference-Cited by-同舟云学术

The first example of ab initio calculations of f–f transitions for the case of [Eu(DOTP)]5− complex—experiment versus theory

Published:2016 Issue:40 Volume:18 Page:27808-27817
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Janicki Rafał¹²³⁴,Kędziorski Andrzej⁵⁶⁷⁸⁹,Mondry Anna¹²³⁴

Affiliation:

1. University of Wrocław

2. Faculty of Chemistry

3. 50-383 Wrocław

4. Poland

5. Nicolaus Copernicus University

6. Faculty of Physics

7. Astronomy and Informatics

8. Address Toruń

9. Institute of Physics

Abstract

Structure, IR and UV-vis-NIR spectra of the [Eu(DOTP)]⁵⁻ complex in single crystals were studied experimentally. Ab initio calculations of the excited states of the [Eu(DOTP)]⁵⁻ complex provide new insights into the interpretation of the observed f–f electronic transitions spectra.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP05284C

Reference72 articles.

1. A. Merbach , L.Helm and E.Toth, The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging, John Wiley & Sons, Ltd, 2013

2. Characterization of Lanthanide(III) DOTP Complexes: Thermodynamics, Protonation, and Coordination to Alkali Metal Ions

3. TmDOTP5- as a23Na shift reagent for the subcutaneously implanted 9L gliosarcoma in rats

4. Development of responsive lanthanide probes for cellular applications

5. Intriguing aspects of lanthanide luminescence

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