LnDOTA puppeteering: removing the water molecule and imposing tetragonal symmetry-Reference-Cited by-同舟云学术

LnDOTA puppeteering: removing the water molecule and imposing tetragonal symmetry

Published:2024 Issue:1 Volume:15 Page:113-123
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Manvell Anna Schannong¹^ORCID,Pfleger Rouven¹²^ORCID,Bonde Niels Andreas¹³^ORCID,Briganti Matteo⁴^ORCID,Mattei Carlo Andrea⁴^ORCID,Nannestad Theis Brock¹^ORCID,Weihe Høgni¹^ORCID,Powell Annie K.²^ORCID,Ollivier Jacques³^ORCID,Bendix Jesper¹^ORCID,Perfetti Mauro⁴^ORCID

Affiliation:

1. Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark

2. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany

3. Institut Laue-Langevin, 71 avenue des Martyrs, CS 20156, 38042 Grenoble Cedex 9, France

4. Department of Chemistry U. Schiff, Via della Lastruccia 3, 50019, Sesto Fiorentino, Italy

Abstract

Ionic strength and solid state packing effects have been used to remove the coordinated water molecule from the LnDOTA complexes, allowing to understand the magnetic anisotropy and single molecule magnet properties of these complexes.

Funder

H2020 European Research Council

Karlsruhe House of Young Scientists

Ministero dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC03928E

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5. Longitudinal and transverse NMR relaxivities of Ln(III)-DOTA complexes: A comprehensive investigation

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