Cobalt catalyzed sp3 C–H amination utilizing aryl azides-Reference-Cited by-同舟云学术

Cobalt catalyzed sp3 C–H amination utilizing aryl azides

Published:2015 Issue:11 Volume:6 Page:6672-6675
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Villanueva Omar¹²³,Weldy Nina Mace¹²³,Blakey Simon B.¹²³,MacBeth Cora E.¹²³

Affiliation:

1. Department of Chemistry

2. Emory University

3. USA

Abstract

A dinuclear Co(ii) complex supported by a modular, tunable redox-active ligand system is capable of selective C–H amination to form indolines from aryl azides in good yields at low (1 mol%) catalyst loading.

Funder

Center for Selective C-H Functionalization, National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01162K

Reference39 articles.

1. Intramolecular C(sp3)–H amination

2. Synthesis of 1,3-Difunctionalized Amine Derivatives through Selective C−H Bond Oxidation

3. Cobalt(II)-Catalyzed Intermolecular Benzylic C−H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)

4. Synthesis of Propargylic and Allenic Carbamates via the C–H Amination of Alkynes

5. N-Tosyloxycarbamates as a Source of Metal Nitrenes: Rhodium-Catalyzed C−H Insertion and Aziridination Reactions

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