Bicarbonate insertion triggered self-assembly of chiral octa-gold nanoclusters into helical superstructures in the crystalline state-Reference-Cited by-同舟云学术

Bicarbonate insertion triggered self-assembly of chiral octa-gold nanoclusters into helical superstructures in the crystalline state

Published:2022 Issue:35 Volume:13 Page:10523-10531
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Si Wei-Dan¹,Sheng Kai²,Zhang Chengkai¹,Wang Zhi¹^ORCID,Zhang Shan-Shan¹,Dou Jian-Min³,Feng Lei¹,Gao Zhi-Yong⁴^ORCID,Tung Chen-Ho¹^ORCID,Sun Di¹^ORCID

Affiliation:

1. Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China

2. School of Aeronautics, Shandong Jiaotong University, Ji'nan 250037, People's Republic of China

3. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, People's Republic of China

4. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, Henan, People's Republic of China

Abstract

A pair of unprecedented helical superstructures via self-assembly of inherently homochiral Au8 nanoclusters, [Au8(R/S-BINAP)3(o-HMBA)2]·2(HCO3), is obtained in the crystalline state, in which the HCO3− ions act as the bridge.

Funder

National Natural Science Foundation of China

Fok Ying Tung Education Foundation

Natural Science Foundation of Shandong Province

Taishan Scholar Project of Shandong Province

Shandong University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03463H