Synthesis of highly reactive polyisobutylene by catalytic chain transfer in hexanes at elevated temperatures; determination of the kinetic parameters-Reference-Cited by-同舟云学术

Synthesis of highly reactive polyisobutylene by catalytic chain transfer in hexanes at elevated temperatures; determination of the kinetic parameters

Published:2017 Issue:18 Volume:8 Page:2852-2859
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Rajasekhar Tota¹²³⁴⁵^ORCID,Emert Jack⁶⁷⁵,Faust Rudolf¹²³⁴⁵

Affiliation:

1. Polymer Science Program

2. Department of Chemistry

3. University of Massachusetts Lowell

4. Lowell

5. USA

6. Infineum USA

7. Linden

Abstract

The rate constants of activation/deactivation for dormant oxonium/active carbenium ions have been measured and related to the increasing polymerization rate with increasing temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PY/C7PY00415J

Reference37 articles.

1. Kinetic and Mechanistic Studies of the Polymerization of Isobutylene Catalyzed by EtAlCl2/Bis(2-chloroethyl) Ether Complex in Hexanes

2. Anomalous carbon numbers in cationic oligomers of propylene and butylenes

3. Negative Ion Electrospray Ionization Mass Spectrum of Polyisobutenylsuccinic Anhydride: Implications for Isobutylene Polymerization Mechanism

4. Alder-ene addition of maleic anhydride to polyisobutene: nuclear magnetic resonance evidence for an unconventional mechanism

5. Highly reactive polyisobutene as a component of a new generation of lubricant and fuel additives

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