Recent advances in green cationic polymerization

Author:

Zhu Yan1,Yu Zhaopeng1,Liu Ruofan1,Jin Yusun1,Shi Qisong1,Wu Yibo1ORCID

Affiliation:

1. The College of New Materials and Chemical Engineering, Beijing Key Lab of Special Elastomer Composite Materials Beijing Institute of Petrochemical Technology Beijing China

Abstract

AbstractTraditional living/controlled cationic polymerization provides a simple synthetic route for the preparation of various polymers with set molecular weight, narrow molecular weight distribution, and clear structure. Nowadays, under the requirements of sustainable development, it is very important to explore the green chemical technology in depth. This review offers an overview of initiation systems, reaction media, polymerization techniques, and monomers, with the aim of summarizing environmentally friendly methods utilized in the field of cationic polymerization over the past 15 years. It covers a variety of directions from traditional initiation systems to green initiators, from corrosive solvents to environmentally friendly solvents, from drop initiation to external stimulation initiation, from petroleum fractionated monomers to bio‐based monomers. These methods and Techniques aim to develop advanced high‐quality polymer products using cationic polymerization, and achieving efficient energy savings and reducing emissions. The ongoing exploration of green‐controlled cationic polymerization holds promise for opening up new avenues and novel technology for high‐performance polyolefin materials.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Publisher

Wiley

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