Dihydrogen contacts observed by through-space indirect NMR coupling

Author:

Dračínský Martin1234ORCID,Buchta Michal1234,Buděšínský Miloš1234,Vacek-Chocholoušová Jana1234,Stará Irena G.1234ORCID,Starý Ivo1234ORCID,Malkina Olga L.5678ORCID

Affiliation:

1. Institute of Organic Chemistry and Biochemistry

2. Czech Academy of Sciences

3. 166 10 Prague 6

4. Czech Republic

5. Institute of Inorganic Chemistry

6. Slovak Academy of Sciences

7. SK-84536 Bratislava

8. Slovakia

Abstract

Through-space NMR indirect couplings between hydrogen atoms formally separated by 18 covalent bonds have been detected. The coupling pathway has been visualised and analysed by computational methods.

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Grantová Agentura České Republiky

Akademie Věd České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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5. Helicenes: Synthesis and Applications

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