Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [ZnIIReIV3] system
Author:
Affiliation:
1. Instituto de Ciencia Molecular (ICMol)/Departament de Química Inorgànica
2. Universitat de València
3. 46980 Paterna
4. Spain
Abstract
The compound (NBu4)4[ZnII{ReIVCl4(μ-ox)}3] (1) [NBu4+ = tetra-n-butylammonium cation and ox2− = oxalate dianion] is the first example of an oxalato-bridged ZnII system coordinated to a 5d metal ion that exhibits slow relaxation of magnetisation.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT03728K
Reference43 articles.
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2. One-Dimensional Oxalato-Bridged Cu(II), Co(II), and Zn(II) Complexes with Purine and Adenine as Terminal Ligands
3. Rational Design of 2D Magnetic Metal−Organic Coordination Polymers Assembled from Oxalato and Dipyridyl Spacers
4. Template-directed synthesis of three new open-framework metal(ii) oxalates using Co(iii) complex as template
5. Template-directed syntheses of two 3D metal oxalates: in situ N-methylation and crystal structures
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