Field-induced slow magnetic relaxation in low-spin S = 1/2 mononuclear osmium(v) complexes

Author:

Su Qian-Qian1234,Fan Kun56789,Huang Xin-Da56789,Xiang Jing1234ORCID,Cheng Shun-Cheung10111213ORCID,Ko Chi-Chiu10111213ORCID,Zheng Li-Min56789ORCID,Kurmoo Mohamedally1415161718,Lau Tai-Chu10111213ORCID

Affiliation:

1. College of Chemistry and Environmental Engineering

2. Yangtze University

3. Jingzhou 434020

4. P. R. China

5. State Key Laboratory of Coordination Chemistry

6. School of Chemistry and Chemical Engineering

7. Collaborative Innovation Center of Advanced Microstructures

8. Nanjing University

9. Nanjing 210093

10. Department of Chemistry

11. City University of Hong Kong

12. Kowloon Tong

13. Hong Kong

14. Institut de Chimie

15. Université de Strasbourg

16. CNRS-UMR7177

17. Strasbourg Cedex 67007

18. France

Abstract

Stable low-spin Os(v) complexes obtained from the photochemical reactions of NO2-OsN showing slow magnetic relaxation behavior.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hubei Province

Research Grants Council, University Grants Committee

National Basic Research Program of China

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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