Excellent yield of a variety of silicon-boron radicals and their reactivity-Reference-Cited by-同舟云学术

Excellent yield of a variety of silicon-boron radicals and their reactivity

Published:2022 Issue:29 Volume:51 Page:11040-11047
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nazish Mohd¹,Ding Yi¹,Legendre Christina M.¹,Kumar Arun¹,Graw Nico¹,Schwederski Brigitte²,Herbst-Irmer Regine¹^ORCID,Parvathy Parameswaran³^ORCID,Parameswaran Pattiyil³^ORCID,Stalke Dietmar¹^ORCID,Kaim Wolfgang²^ORCID,Roesky Herbert W.¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, Göttingen 37077, Germany

2. Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, Stuttgart 70569, Germany

3. National Institute of Technology Calicut, Kozhikode, Kerala 673601, India

Abstract

Silicon-boron radicals have been synthesized in high excess yield through one-pot reduction using different halogen and organic substituents. Further Si–B radical undergoes oxidative addition of bromine and selenium leading to the formation of compounds 4 and 5.

Funder

Danmarks Grundforskningsfond

Fonds der Chemischen Industrie

National Institute of Technology Calicut

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01318E

Reference61 articles.

1. P. P.Gaspar and R.West , ed. Z. Rappoport and Y. Apeloig , John Wiley and Sons , The Chemistry of Organic Silicon Compounds, Chichester , 1998 , vol. 2, Part 3 , pp. 2463–2567

2. Stable Silylenes

3. Chemistry of thermally stable bis(amino)silylenes

4. Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

5. An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

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