Effect of chemical environment on the radiation chemistry of N,N-di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention-Reference-Cited by-同舟云学术

Effect of chemical environment on the radiation chemistry of N,N-di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention

Published:2019 Issue:38 Volume:48 Page:14450-14460
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Horne Gregory P.¹²³⁴^ORCID,Zarzana Christopher A.¹²³⁴^ORCID,Grimes Travis S.¹²³⁴^ORCID,Rae Cathy¹²³⁴^ORCID,Ceder Joakim¹²³⁴⁵^ORCID,Mezyk Stephen P.⁶⁷⁸⁴^ORCID,Mincher Bruce J.¹²³⁴^ORCID,Charbonnel Marie-Christine⁹¹⁰¹¹^ORCID,Guilbaud Philippe⁹¹⁰¹¹^ORCID,Saint-Louis George⁹¹⁰¹¹,Berthon Laurence⁹¹⁰¹¹^ORCID

Affiliation:

1. Idaho National Laboratory

2. Center for Radiation Chemistry Research

3. Idaho Falls

4. USA

5. KTH Royal Institute of Technology

6. California State University Long Beach

7. Department of Chemistry and Biochemistry

8. Long Beach

9. CEA, DEN, DMRC

10. Univ Montpellier

11. France

Abstract

Gamma-radiolysis of the ligand DEHBA is accelerated under biphasic acidic conditions and yields one or more plutonium complexing degradation products.

Funder

U.S. Department of Energy

Nuclear Energy University Programs

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02383F

Reference31 articles.

1. REVIEW ARTICLE LONG CHAIN DISUBSTITUTED ALIPHATIC AMIDES AS EXTRACTING AGENTS IN INDUSTRIAL APPLICATIONS OF SOLVENT EXTRACTION

2. Comparing Branched versus Straight-chained Monoamide Extractants for Actinide Recovery