Reactions of the ˙NO<sub>3</sub> radical with nuclear extraction ligands in alkane solution-Reference-Cited by-同舟云学术

Reactions of the ˙NO₃ radical with nuclear extraction ligands in alkane solution

Published:2024 Issue:35 Volume:26 Page:23003-23009
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Dang Anh N.¹^ORCID,Rogalski Maya H.¹^ORCID,Peterman Dean R.²^ORCID,Mincher Bruce J.²^ORCID,Mezyk Stephen P.¹^ORCID

Affiliation:

1. California State University at Long Beach, Department of Chemistry and Biochemistry, 1250 N. Bellflower Blvd., Long Beach, CA, 90840, USA

2. Idaho National Laboratory, Center for Radiation Chemistry Research, PO Box 1625, Idaho Falls, ID, 83415, USA

Abstract

First-ever rate constant data for NO3˙ radical reactions with organophosphorus and amidic extraction ligands in liquid n-dodecane. Reaction mechanisms were identified as H-atom (amidic) and electron (phosphorus) abstraction based on DFT calculations.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00751D

Reference47 articles.

1. E. R.Irish and W. H.Reas , The PUREX process: A Solvent Extraction Reprocessing Method for Irradiated Uranium , Hanford Atomic Products Operation , Hanford WA , 1957

2. W. W.Schulz and J. D.Navratil , Science and Technology of Tributyl Phosphate , CRC Press , Boca Raton, FL, USA , 1984

3. R. R.Shoun and W. J.McDowell , Actinide Extractants: Development, Comparison and Future , Actinide Separations, ACS Symposium Series 17 , American Chemical Society , Washington D.C., USA , 1980 , ch. 6

4. Recovery of rare earths from nitric acid leach solutions of phosphate ores using solvent extraction with a new amide extractant (TODGA)

5. The Effect of Alkyl Substituents on Actinide and Lanthanide Extraction by Diglycolamide Compounds