Direct enantiospecific substitution of primary α-aminoalkylferrocenes via Lewis acid-catalyzed C

Direct enantiospecific substitution of primary α-aminoalkylferrocenes via Lewis acid-catalyzed C–N bond cleavage

Published:2014-10-06 Issue:93 Volume:50 Page:14531-14534
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Zhou Meng-Guang,Zhang Wen-Zhao,Tian Shi-Kai

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC07196D

Reference67 articles.

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2. M. B. Smith and J.March, March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, John Wiley & Sons, Hoboken, NJ, 6th edn, 2007

3. Although C(sp3)–N bond cleavage has been applied in protective group chemistry, alkylamines have rarely been employed directly as sp3 hybridized carbon electrophiles to couple with nucleophiles. See: P. G. M.Wuts and T. W.Greene, Greene's Protective Groups in Organic Synthesis, John Wiley & Sons, Hoboken, NJ, 4th edn, 2007

4. Novel 5-Dimethylamino-1- and 2-Indanyl Uracil Derivatives

5. Deaminative and Decarboxylative Catalytic Alkylation of Amino Acids with Ketones

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