Reductive nitrosylation of nickel(ii) complex by nitric oxide followed by nitrous oxide release-Reference-Cited by-同舟云学术

Reductive nitrosylation of nickel(ii) complex by nitric oxide followed by nitrous oxide release

Published:2016 Issue:25 Volume:45 Page:10200-10208
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghosh Somnath¹²³,Deka Hemanta¹²³,Dangat Yuvraj B.⁴⁵⁶³,Saha Soumen¹²³,Gogoi Kuldeep¹²³,Vanka Kumar⁴⁵⁶³,Mondal Biplab¹²³

Affiliation:

1. Department of Chemsitry

2. Indian Institute of Technology Guwahati

3. India

4. Academy of Scientific and Innovative Research

5. National Chemical Laboratory

6. Pune 411008

Abstract

Ni(ii) complex of bis-(2-ethyl-4-methylimidazol-5-yl)methane in methanol undergoes reductive nitrosylation in presence of NO to afford the corresponding Ni(i)-nitrosyl intermediate. Subsequent reaction with additional NO releases N₂O with Ni(ii)-nitrito complex formation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00826G

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