Nickel-mediated N–N bond formation and N2O liberation via nitrogen oxyanion reduction-Reference-Cited by-同舟云学术

Nickel-mediated N–N bond formation and N2O liberation via nitrogen oxyanion reduction

Published:2021 Issue:31 Volume:12 Page:10664-10672
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Beagan Daniel M.¹²³⁴,Cabelof Alyssa C.¹²³⁴,Pink Maren¹²³⁴,Carta Veronica¹²³⁴,Gao Xinfeng¹²³⁴^ORCID,Caulton Kenneth G.¹²³⁴^ORCID

Affiliation:

1. Indiana University

2. Department of Chemistry

3. Bloomington

4. USA

Abstract

Deoxygenation of nitrogen oxyanions coordinated to nickel using reduced borylated heterocycles leads to N–N bond formation and N₂O liberation. The nickel dimer product facilitates NO disproportionation, leading to a synthetic cycle.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02846D

Reference70 articles.

1. A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst

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