Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a CuII–aminyl-iminosemiquinone complex-Reference-Cited by-同舟云学术

Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a CuII–aminyl-iminosemiquinone complex

Published:2021 Issue:11 Volume:57 Page:1352-1355
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sarkar Prasenjit¹²³⁴^ORCID,Sarmah Amrit⁵⁶⁷⁸⁹,Mukherjee Chandan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Guwahati

3. Guwahati

4. India

5. Department of Molecular Modelling

6. Institute of Organic Chemistry and Biochemistry ASCR

7. v.v.i. Flemingovo nám. 2

8. CZ-166 10 Prague 6

9. Czech Republic

Abstract

A thermodynamically unstable amine radical and an iminosemiquinone radical-coordinated square pyramidal Cu(ii) complex are isolated and established by X-ray crystallography, magnetic and EPR measurements, and DFT calculations.

Funder

Department of Biotechnology, Ministry of Science and Technology, India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC07378D

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