A local point of view of the Cu(100) → NiTPP charge transfer at the NiTPP/Cu(100) interface-Reference-Cited by-同舟云学术

A local point of view of the Cu(100) → NiTPP charge transfer at the NiTPP/Cu(100) interface

Published:2023 Issue:39 Volume:25 Page:26779-26786
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Carlotto Silvia¹²^ORCID,Verdini Alberto³^ORCID,Zamborlini Giovanni⁴^ORCID,Cojocariu Iulia⁵⁶^ORCID,Feyer Vitaliy⁷⁸^ORCID,Floreano Luca⁹^ORCID,Casarin Maurizio¹^ORCID

Affiliation:

1. University of Padova, Department of Chemical Sciences, via F. Marzolo 1, 35131, Padova, Italy

2. ICMATE - CNR c/o University of Padova, Department of Chemical Sciences, via F. Marzolo 1, via F. Marzolo 1, 35131, Padova, Italy

3. IOM – CNR c/o University of Perugia, Department of Physics and Geology, via A. Pascoli, 06123, Perugia, Italy

4. TU Dortmund University, Department of Physics, Otto-Hahn-Straβe 4, 44227 Dortmund, Germany

5. University of Trieste, Department of Physics, Via A. Valerio 2, 34127 Trieste, Italy

6. Elettra-Sincrotrone, S.C.p.A., S.S. 14 - km 163.5, 34149 Trieste, Italy

7. Forschungszentrum Jülich GmbH, Peter Grünberg Institute (PGI-6), Leo-Brandt-Straβe, 52428 Jülich, Germany

8. Duisburg-Essen University, Department of Physics and Center for Nanointegration Duisburg-Essen (CENIDE), 47048 Duisburg, Germany

9. CNR – IOM, Lab. TASC, Basovizza S.S. 14, km 163.5, 34149 Trieste, Italy

Abstract

The chemisorption site of NiTPP on Cu(100) has been determined by combining symmetry considerations with photoelectron diffraction. The Ni(ii)→Ni(i) reduction at the interface rules the adsorption sites and the NiTPP orientation on the substrate.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP04021F

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