Rare-earth metal-mediated PhCN insertion into N,N-bis(trimethylsilyl)naphthalene-1,8-diamido dianion – a synthetic approach to complexes coordinated by ansa-bridged amido-amidinato ligand
Author:
Affiliation:
1. Institute of Organometallic Chemistry of Russian Academy of Sciences
2. Nizhny Novgorod
3. Russia
4. Institute of Organoelement compounds of Russian Academy of Sciences
5. Moscow
Abstract
We report the first example of rare earth metal-mediated insertion of PhCN into Si–N bonds with the formation of an amidinato moiety.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT03809G
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