Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697, United States
Funder
Basic Energy Sciences
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b01966
Reference37 articles.
1. Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th}1− anion containing thorium in the formal +2 oxidation state
2. Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C5H4SiMe3)3U]
3. Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ Backbonding
4. Expanding the Chemistry of Molecular U2+Complexes: Synthesis, Characterization, and Reactivity of the {[C5H3(SiMe3)2]3U}−Anion
5. Identification of the Formal +2 Oxidation State of Plutonium: Synthesis and Characterization of {PuII[C5H3(SiMe3)2]3}−
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