Chemoselective semihydrogenation of alkynes catalyzed by manganese(i)-PNP pincer complexes
Author:
Affiliation:
1. Leibniz-Institut für Katalyse e.V
2. Rostock
3. Germany
4. F. Hoffmann-La Roche AG
5. Department of Process Chemistry & Catalysis
6. Basel
7. Switzerland
Abstract
A first homogeneous manganese catalyzed chemoselective semihydrogenation of alkynes to Z-olefins in the presence of molecular hydrogen is described.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY00992J
Reference91 articles.
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3. P. G. Andersson and I. J.Munslow , in Modern Reduction Methods , Wiley , New York , 2008
4. Are Alkyne Reductions Chemo-, Regio-, and Stereoselective Enough To Provide Pure (Z)-Olefins in Polyfunctionalized Bioactive Molecules?
5. Ein neuer Katalysator für selektive Hydrierungen
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