Iridium motif linked porphyrins for efficient light-driven hydrogen evolution via triplet state stabilization of porphyrin

Author:

Tritton Daniel Nnaemaka1234,Bodedla Govardhana Babu1234ORCID,Tang Geliang5678ORCID,Zhao Jianzhang5678ORCID,Kwan Chak-Shing1234,Leung Ken Cham-Fai1234ORCID,Wong Wai-Yeung12349ORCID,Zhu Xunjin1234ORCID

Affiliation:

1. Department of Chemistry

2. Hong Kong Baptist University

3. Kowloon Tong

4. P. R. China

5. School of Chemical Engineering

6. Dalian University of Technology

7. Dalian

8. China

9. Department of Applied Biology & Chemical Technology

Abstract

New iridium motif linked porphyrin TBPyZnP-Ir is developed for highly efficient photocatalytic hydrogen evolution (PHE) coupled with non-noble-metal cobaloxime co-catalyst.

Funder

National Natural Science Foundation of China

Hong Kong Polytechnic University

Research Grants Council, University Grants Committee

Hong Kong Baptist University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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