Grignard coupling-based synthesis of vinyl-substituted hydridopolycarbosilane: effect of starting material and polymerization behavior-Reference-Cited by-同舟云学术

Grignard coupling-based synthesis of vinyl-substituted hydridopolycarbosilane: effect of starting material and polymerization behavior

Published:2021 Issue:19 Volume:11 Page:11771-11778
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Jeong Minji¹²³⁴⁵,Choi Moon-Gun¹²³⁴,Lee Yoonjoo⁵⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Yonsei University

3. Seoul

4. Republic of Korea

5. Energy & Environmental Division

6. Korea Institute of Ceramic Engineering & Technology

7. Jinju

Abstract

Polymerization of VHPCS by the Grignard coupling reaction depended on the type of starting material. In the case of Cl₃SiCH₂Cl starting material, a stepwise growth manner was shown, due to a coupling between –CH₂Cl and the Si–Cl sites.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA00244A

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