Role of Au–Sn bonding for stabilizing a gold nanocatalyst: a reinvestigation of purple of Cassius-Reference-Cited by-同舟云学术

Role of Au–Sn bonding for stabilizing a gold nanocatalyst: a reinvestigation of purple of Cassius

Published:2022 Issue:38 Volume:51 Page:14747-14752
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Huan¹^ORCID,Zhang Fengwei¹^ORCID,Guo Li²^ORCID,Han Bo³,Yan Shuai-Ting¹,Zhang Xian-Ming¹

Affiliation:

1. Institute of Crystalline Materials, Shanxi University, Taiyuan 030006, Shanxi, People's Republic of China

2. Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China

3. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, Hubei, People's Republic of China

Abstract

The ancient pigment, purple of Cassius is redefined as tin confined Au nanoparticles through Au–Sn bonding. It has also shown excellent activity and selectivity in hydration of alkyne.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01759H

Reference63 articles.

1. Gold in a Metallic Divided State—From Faraday to Present-Day Nanoscience

2. Nanotechnology: from the ancient time to nowadays

3. Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology

4. Gold—an introductory perspective

5. The true story of Purple of Cassius

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