Carbon dioxide cleavage across a tungsten-alkylidyne bearing a trianionic pincer-type ligand-Reference-Cited by-同舟云学术

Carbon dioxide cleavage across a tungsten-alkylidyne bearing a trianionic pincer-type ligand

Published:2016 Issue:40 Volume:45 Page:15783-15785
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gonsales Stella A.¹²³⁴⁵,Ghiviriga Ion¹²³⁴⁵,Abboud Khalil A.¹²³⁴⁵,Veige Adam S.¹²³⁴⁵

Affiliation:

1. University of Florida

2. Department of Chemistry

3. Center for Catalysis

4. Gainesville

5. USA

Abstract

Splitting of CO₂ across the tungsten-carbon triple bond in [CF₃-ONO]WCC^tBu(THF)₂ (1) yields the tungsten oxo ketene [CF₃-ONO]W(O){(CH₃)₃CCCO} (6).

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01049K

Reference40 articles.

1. J. F. Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis, University Science Books, Sausalito, 2010

2. Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenyl

3. Rapid reversible fission of a C–H bond in a metal complex: X-ray crystal structure of [RhHCl(But2PCH2CH2CHCH2CH2PBut2)]

4. Large-ring and cyclometalated rhodium complexes from some medium-chain .alpha.,.omega.-diphosphines

5. Transition metal–carbon bonds. Part 52. Large ring and cyclometallated complexes formed from But2PCH2CH2CHRCH2CH2PBut2(R  H or Me) and IrCl3, or [Ir2Cl4(cyclo-octene)4] : crystal structures of the cyclometallated hydride, [IrHCl(But2PCH2CH2CHCH2CH2PBut2)], and the carbene complex [IrCl(But2PCH2CH2CCH2CH2PBut2)]

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