Memorized chiral arrangement of gemini surfactant assemblies in nanometric hybrid organic

Memorized chiral arrangement of gemini surfactant assemblies in nanometric hybrid organic–silica helices

Published:2016 Issue:34 Volume:52 Page:5800-5803
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ryu Naoya¹²³⁴⁵,Okazaki Yutaka¹²³⁴,Hirai Kana¹²³⁴,Takafuji Makoto¹²³⁴⁶,Nagaoka Shoji¹²³⁴⁵,Pouget Emilie⁷⁸⁹¹⁰¹¹,Ihara Hirotaka¹²³⁴⁶,Oda Reiko⁷⁸⁹¹⁰¹¹

Affiliation:

1. Department of Applied Chemistry and Biochemistry

2. Kumamoto University

3. Chuo-ku Kumamoto 860-8555

4. Japan

5. Materials Development Department

6. Kumamoto Institute for Photo-Electro Organics (PHOENICS)

7. Institute of Chemistry & Biology of Membranes & Nanoobjects (UMR5248 CBMN)

8. CNRS

9. Université de Bordeaux

10. Institut Polytechnique Bordeaux

11. 33607 Pessac

Abstract

The chiral arrangement of non-chiral gemini surfactant molecules induced by enantiomeric tartrate counterions was maintained by hybridization with silica matrices even after the removal of the counterions as chiral sources.

Funder

Japan Society for the Promotion of Science

Centre National de la Recherche Scientifique

Université de Bordeaux

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC01219A

Reference36 articles.

1. Emerging chirality in nanoscience

2. Chiral Nanoarchitectonics: Towards the Design, Self-Assembly, and Function of Nanoscale Chiral Twists and Helices

3. Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications

4. Controlled synthesis and photocatalytic investigation of different-shaped one-dimensional titanic acid nanomaterials

5. Enantioselective Artificial Metalloenzymes Based on a Bovine Pancreatic Polypeptide Scaffold

Cited by 23 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Imparting chiroptical property to achiral azobenzene derivative via incorporation into chiral-controlled helical nanofibers;Bulletin of the Chemical Society of Japan;2024-07

2. Porphyrin-Based Hybrid Nanohelices: Cooperative Effect between Molecular and Supramolecular Chirality on Amplified Optical Activity;The Journal of Physical Chemistry B;2024-01-31

3. Chirality induction to porphyrin derivatives co-confined at the air–water interface with silica nano-helices: towards enantioselective thin solid film surfaces;Nanoscale;2024

4. Organic chiral nano- and microfilaments: types, formation, and template applications;Materials Horizons;2024

5. Induced circular dichroism from helicoidal nano substrates to porphyrins: the role of chiral self-assembly;Nanoscale;2023