Tandem elimination-oxidation of tertiary benzylic alcohols with an oxoammonium salt
Author:
Affiliation:
1. Department of Chemistry
2. Syracuse University
3. 1-014 Center for Science and Technology
4. Syracuse
5. USA
Abstract
Tertiary benzylic alcohols react with oxoammonium salts, undergoing a tandem elimination/allylic oxidation to provide an allylic ether product in a single step.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00965F
Reference38 articles.
1. Oxoammonium Salts. 6.1 4-Acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium Perchlorate: A Stable and Convenient Reagent for the Oxidation of Alcohols. Silica Gel Catalysis
2. PREPARATION OF 4-ACETYLAMINO-2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXOAMMONIUM TETRAFLUOROBORATE, AND THE OXIDATION OF GERANIOL TO GERANIAL
3. Mechanism of the Oxidation of Alcohols by Oxoammonium Cations
4. Oxoammonium Salt Oxidations of Alcohols in the Presence of Pyridine Bases
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