Alkylation of the α-amino C–H bonds of anilines photocatalyzed by a DMEDA-Cu-benzophenone complex: reaction scope and mechanistic studies-Reference-Cited by-同舟云学术

Alkylation of the α-amino C–H bonds of anilines photocatalyzed by a DMEDA-Cu-benzophenone complex: reaction scope and mechanistic studies

Published:2021 Issue:26 Volume:19 Page:5800-5805
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Abadie Baptiste¹²³⁴⁵,Jonusauskas Gediminas⁶⁷³⁴⁵^ORCID,McClenaghan Nathan D.¹²³⁴⁵^ORCID,Toullec Patrick Y.¹²³⁴⁵^ORCID,Vincent Jean-Marc¹²³⁴⁵^ORCID

Affiliation:

1. Institut des Sciences Moléculaires

2. CNRS UMR 5255

3. Univ. Bordeaux

4. 33405 Talence

5. France

6. Laboratoire Ondes et Matière d'Aquitaine

7. CNRS UMR 5798

Abstract

The Cu(ii) complex 1 incorporating a BP chromophore is a highly active photocatalyst for the alkylation of α-amino C–H bonds of anilines. Mechanistic studies revealed the spectroscopic signatures of the key reaction intermediates.

Funder

Centre National de la Recherche Scientifique

Université de Bordeaux

Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00960E

Reference43 articles.

1. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

2. Organic Photoredox Catalysis

3. Visible light photoredox catalysis: applications in organic synthesis

4. Cooperative photoredox catalysis

5. Photoredox Catalysis for Building C–C Bonds from C(sp2)–H Bonds

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Photogeneration of Chlorine Radical from a Self‐Assembled Fluorous 4CzIPN•Chloride Complex: Application in C−H Bond Functionalization;Angewandte Chemie International Edition;2024-05-21

2. Photogeneration of Chlorine Radical from a Self‐Assembled Fluorous 4CzIPN•Chloride Complex: Application in C−H Bond Functionalization;Angewandte Chemie;2024-05-21

3. Decatungstate‐Photocatalyzed Diastereoselective Dearomative Hydroalkylation of Indoles;European Journal of Organic Chemistry;2024-05-17

4. Photocatalytic α-aminoalkyl radical addition of amines mediated by benzophenone under visible light;Green Chemistry;2024

5. Recent Advances in Carbonyl‐Photoredox/Transition Metal Dual Catalysis;Asian Journal of Organic Chemistry;2023-07-14