Decatungstate‐Photocatalyzed Diastereoselective Dearomative Hydroalkylation of Indoles-Reference-Cited by-同舟云学术

Decatungstate‐Photocatalyzed Diastereoselective Dearomative Hydroalkylation of Indoles

Published:2024-05-17 Issue:22 Volume:27 Page:
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur J Org Chem

Author:

Montinho‐Inacio Emeric¹,Bouchet Damien¹,Ma Wei‐Yang¹,Retailleau Pascal¹,Neuville Luc¹²,Masson Géraldine¹²^ORCID

Affiliation:

1. Institut de Chimie des Substances Naturelles (ICSN) CNRS Université Paris-Saclay 1 Avenue de la Terrasse 91198 Gif-sur-Yvette Cedex France

2. HitCat, Seqens-CNRS joint laboratory Seqens'Lab 8 Rue de Rouen 78440 Porcheville France

Abstract

AbstractIn this study, we present an efficient and straightforward dearomative hydroalkylation of indoles. By utilizing alkanes or ethers as alkyl radical sources and employing TBADT as a cost‐effective photocatalyst for direct hydrogen atom transfers (HAT), we achieved successful conversion of these heterocyclic derivatives into 2‐alkylindolines with good to excellent yields and high diastereoselectivity under mild reaction conditions.

Publisher

Wiley

Reference198 articles.

1. For selected reviews on indole dearomatization see:

2. Advances in dearomatization strategies of indoles

3. Synthesis of Spirocyclic Indolenines

4. Palladium-Catalyzed Dearomatizing Difunctionalization of Indoles and Benzofurans

5. Recent advances in spirocyclization of indole derivatives

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