Effect of the coordination environment of Cu in Cu2O on the electroreduction of CO2 to ethylene

Author:

Wu Yahui12345,Chen Chunjun12345,Yan Xupeng12345,Liu Shoujie678,Chu Mengen91011128,Wu Haihong91011128ORCID,Ma Jun12345,Han Buxing12345ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. CAS Key Laboratory of Colloid and Interface and Thermodynamics

3. CAS Research/Education Center for Excellence in Molecular Sciences

4. Institute of Chemistry

5. Chinese Academy of Sciences

6. Chemistry and Chemical Engineering of Guangdong Laboratory

7. Shantou 515063

8. China

9. Shanghai Key Laboratory of Green Chemistry and Chemical Processes

10. School of Chemistry and Molecular Engineering

11. East China Normal University

12. Shanghai 200062

Abstract

The coordination number (CN) of Cu–Cu and Cu–O in Cu2O play crucial role on the catalytic performance of CO2 electrocatalytic reduction to C2H4. And the CN of Cu–Cu and Cu–O could be tuned by changing the crystal surface and size of Cu2O.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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