Rare-earth–iridium heterobimetallic complexes with bridging imido and silylmethyl ligands: synthesis, structure and reactivity-Reference-Cited by-同舟云学术

Rare-earth–iridium heterobimetallic complexes with bridging imido and silylmethyl ligands: synthesis, structure and reactivity

Published:2015 Issue:10 Volume:39 Page:7608-7616
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Shima Takanori¹²³⁴⁵,Yanagi Takako¹²³⁴,Hou Zhaomin¹²³⁴⁵

Affiliation:

1. Organometallic Chemistry Laboratory

2. RIKEN

3. Wako

4. Japan

5. Advanced Catalysis Research Group

Abstract

The reaction of [(C₅Me₅)IrN^tBu] with [(C₅Me₄R)Ln(CH₂SiMe₃)₂(THF)] (Ln = Lu, Sc; R = Me, SiMe₃) afforded novel heterometallic rare earth–iridium imido complexes, which show unique structural features and reactivities.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ00598A

Reference62 articles.

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