Redox and acid–base properties of asymmetric non-heme (hydr)oxo-bridged diiron complexes-Reference-Cited by-同舟云学术

Redox and acid–base properties of asymmetric non-heme (hydr)oxo-bridged diiron complexes

Published:2014 Issue:25 Volume:43 Page:9740-9753
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Jozwiuk Anna¹²³,Ingram Audrey L.¹²³,Powell Douglas R.¹²³,Moubaraki Boujemaa⁴⁵⁶,Chilton Nicholas F.⁴⁵⁶,Murray Keith S.⁴⁵⁶,Houser Robert P.¹⁷⁸

Affiliation:

1. Department of Chemistry & Biochemistry

2. University of Oklahoma

3. Norman, USA

4. Chemistry Department

5. Monash University

6. Clayton, Australia

7. University of Northern Colorado

8. Greeley, USA

Abstract

[(FeL)₂(μ-OH)]⁺, [(FeL)₂(μ-O)] and [(FeL^NO2)₂(μ-OH)]⁺, were synthesized and characterized. Electrochemical and chemical reduction of [(FeL)₂(μ-OH)]BPh₄ revealed disproportionation followed by proton transfer, and [(FeL)₂(μ-O)] was formed upon exposure to oxygen.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00047A

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