Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates-Reference-Cited by-同舟云学术

Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates

Published:2019 Issue:17 Volume:48 Page:5692-5697
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Plajer Alex J.¹²³,Kopf Sara¹²³,Colebatch Annie L.¹²³^ORCID,Bond Andrew D.¹²³^ORCID,Wright Dominic S.¹²³^ORCID,García-Rodríguez Raúl⁴⁵⁶⁷⁸^ORCID

Affiliation:

1. Chemistry Department. Cambridge University

2. Cambridge CB2 1EW

3. UK

4. GIR MIOMeT-IU Cinquima-Química Inorgánica Facultad de Ciencias

5. Universidad de Valladolid

6. Campus Miguel

7. Delibes

8. 47011 Valladolid

Abstract

Reactions of aluminate anions [EtAl(6-R-2-py)₃]⁻(6-R-2-py = 6-R-2-pyridyl, R = Me or Br) with aldehydes (RCHO) or carboxylic acids (RCO₂H) reveal how these species can be used to sense chirality and show a new aspect of isomerism in this area.

Funder

Ministerio de Economía y Competitividad

European Social Fund

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00869A

Reference31 articles.

1. Tris(2-pyridyl) tripod ligands1Dedicated to Daryle H. Busch on the occasion of his 70th birthday.1