Synthesis of tris(3-pyridyl)aluminate ligand and its unexpected stability against hydrolysis: revealing cooperativity effects in heterobimetallic pyridyl aluminates-Reference-Cited by-同舟云学术

Synthesis of tris(3-pyridyl)aluminate ligand and its unexpected stability against hydrolysis: revealing cooperativity effects in heterobimetallic pyridyl aluminates

Published:2021 Issue:37 Volume:50 Page:13059-13065
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

García-Romero Álvaro¹,Martín-Álvarez Jose M.¹^ORCID,Colebatch Annie L.²³^ORCID,Plajer Alex J.⁴,Miguel Daniel¹^ORCID,Álvarez Celedonio M.¹^ORCID,García-Rodríguez Raúl¹^ORCID

Affiliation:

1. GIR MIOMeT-IU Cinquima-Química Inorgánica Facultad de Ciencias, Universidad de Valladolid; Campus Miguel Delibes, 47011 Valladolid, Spain

2. Chemistry Department. Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK

3. Research School of Chemistry. Australian National University, Canberra, ACT, 2601, Australia

4. Chemical Research Laboratory, 12 Mansfield Road, Oxford, OX1 3TA, UK

Abstract

Bimetallic cooperativity provides a reason for the unexpected water stability of the tris(3-pyridyl)aluminate [EtAl(3-py)3]− (3-py = 3-pyridyl) (1), the first reported member of the anionic tris(3-pyridyl) ligand family.

Funder

Ministerio de Ciencia, Innovación y Universidades

Ministerio de Economía y Competitividad

Agencia Estatal de Investigación

European Social Fund

Universidad de Valladolid

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02351A