Uranium(<scp>iv</scp>) alkyl cations: synthesis, structures, comparison with thorium(<scp>iv</scp>) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity-Reference-Cited by-同舟云学术

Uranium(iv) alkyl cations: synthesis, structures, comparison with thorium(iv) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity

Published:2022 Issue:46 Volume:13 Page:13748-13763
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Andreychuk Nicholas R.¹,Vidjayacoumar Balamurugan¹,Price Jeffrey S.¹,Kervazo Sophie²,Peeples Craig A.³,Emslie David J. H.¹^ORCID,Vallet Valérie²^ORCID,Gomes André S. P.²^ORCID,Réal Florent²^ORCID,Schreckenbach Georg³^ORCID,Ayers Paul W.¹^ORCID,Vargas-Baca Ignacio¹^ORCID,Jenkins Hilary A.¹,Britten James F.¹

Affiliation:

1. Department of Chemistry, McMaster University, 1280 Main St. West, Hamilton, L8S 4M1, Ontario, Canada

2. Université Lille, UMR 8523 – Physique des Lasers Atoms et Molecules, F-59000 Lille, France

3. Department of Chemistry, University of Manitoba, Winnipeg, R3T 2N2, Manitoba, Canada

Abstract

Uranium(iv) alkyl cations have been prepared, and arene solvent coordination was shown to have a major impact on ethylene polymerization activity. Actinide-arene binding was studied experimentally in the solid state and solution, and computationally.

Funder

Compute Canada

LabEx Chimie des Systèmes Complexes

Natural Sciences and Engineering Research Council of Canada

Canada Research Chairs

Government of Ontario

McMaster University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04302E

Reference98 articles.

1. A quarter-century long story of bis(alkyl) rare-earth (III) complexes

2. Transition metal complexes bearing tridentate ligands for precise olefin polymerization

3. Zirconium complexes in homogeneous ethylene polymerization

4. I. D.Burdett and R. S.Eisinger , in Handbook of Industrial Polyethylene and Technology: Definitive Guide to Manufacturing, Properties, Processing, Applications and Markets , ed. M. A. Spalding and A. M. Chatterjee , Scrivener Publishing , Beverly, MA , 2018 , ch. 3, p. 61

5. J. M.Asua , Polymer Reaction Engineering , Blackwell Publishing , Ames, Iowa , 2007

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