Neutral six-coordinate bis(dithiocarbamato)silicon(iv) complexes with an SiCl2S4 skeleton-Reference-Cited by-同舟云学术

Neutral six-coordinate bis(dithiocarbamato)silicon(iv) complexes with an SiCl2S4 skeleton

Published:2017 Issue:27 Volume:46 Page:8751-8755
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Baus Johannes A.¹²³⁴,Tacke Reinhold¹²³⁴

Affiliation:

1. Universität Würzburg

2. Institut für Anorganische Chemie

3. 97074 Würzburg

4. Germany

Abstract

The first six-coordinate bis(dithiocarbamato)silicon(iv) complexes, compounds 3 and 4 with their unprecedented SiCl₂S₄ skeleton, were synthesised and structurally characterised.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT03264H

Reference45 articles.

1. Pentacoordination of Silicon by Four Covalent Si−S Bonds and One Covalent Si−C Bond

2. Zwitterionic λ5Si-Silicates withSiO2S2C Skeletons: Syntheses and Structural Characterization in the Solid State

3. Synthesis and structure of the first pentacoordinate thiasiliranides

4. New Zwitterionic Spirocyclic λ5Si-Silicates with an SiX4C Skeleton (X = S, O) Containing Two Ligands of the Dithiolato(2−) or Diolato(2−) Type: Synthesis, Structure, and Bonding Situation

5. Zwitterionic λ5Si-Silicates with an SiS4C or SiS2O2C Skeleton, Compounds Containing a Square-Pyramidal or Trigonal-Bipyramidal Si-Coordination Polyhedron

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