Diaryl dithiocarbamates: synthesis, oxidation to thiuram disulfides, Co(<scp>iii</scp>) complexes [Co(S2CNAr2)3] and their use as single source precursors to CoS2-Reference-Cited by-同舟云学术

Diaryl dithiocarbamates: synthesis, oxidation to thiuram disulfides, Co(iii) complexes [Co(S₂CNAr₂)₃] and their use as single source precursors to CoS₂

Published:2022 Issue:34 Volume:51 Page:13061-13070
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sarker Jagodish C.¹²^ORCID,Nash Rosie¹,Boonrungsiman Suwimon³,Pugh David¹^ORCID,Hogarth Graeme¹^ORCID

Affiliation:

1. Department of Chemistry, King's College London, Britannia House, 7 Trinity Street, London SE1 1DB, UK

2. Department of Chemistry, Jagannath University, Dhaka-1100, Bangladesh

3. Centre for Ultrastructural Engineering, King's College London, New Hunt's House, London SE1 1UL, UK

Abstract

Air and moisture stable diaryl dithiocarbamate salts, Ar2NCS2Li, result from addition of CS2 to Ar2NLi. They react cleanly to afford [Co(S2CNAr2)3] which decompose in amine solutions to give CoS2.

Funder

Commonwealth Scholarship Commission

King's College London

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01767A

Reference85 articles.

1. Transition Metal Dithiocarbamates: 1978-2003