Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides-Reference-Cited by-同舟云学术

Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides

Published:2014 Issue:53 Volume:50 Page:7014-7016
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Pelties Stefan¹²³,Herrmann Dirk¹²³,de Bruin Bas⁴⁵⁶,Hartl František⁷⁸⁹,Wolf Robert¹²³

Affiliation:

1. University of Regensburg

2. Institute of Inorganic Chemistry

3. 93040 Regensburg, Germany

4. University of Amsterdam

5. Van't Hoff Institute for Molecular Sciences

6. 1098 XH Amsterdam, The Netherlands

7. University of Reading

8. Department of Chemistry

9. Reading, UK

Abstract

The reaction of white phosphorus with a mononuclear cyclopentadienyl nickel(i) complex affords a nickel-substituted tetraphospha[1.1.0]bicyclobutane in a highly selective fashion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC02601B

Reference49 articles.

1. Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

2. P4 Activation by Late-Transition Metal Complexes

3. P4 Activation by Main Group Elements and Compounds

4. Organometallic pnicogen complexes. VII. Synthesis, structure and bonding of the cubane-like metal cluster tetra-.mu.3-phosphido-tetra-.pi.-pentahaptocyclopentadienyl tetracobalt(III) [Co4(h5-C5H5)4P4]. First reported organometallic complex containing a naked phosphorus atom as a ligand

5. Hexaphosphabenzene as Complex Ligand

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