Biomimetic hydrogen-bonding cascade for chemical activation: telling a nucleophile from a base-Reference-Cited by-同舟云学术

Biomimetic hydrogen-bonding cascade for chemical activation: telling a nucleophile from a base

Published:2021 Issue:2 Volume:12 Page:590-598
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Park Hyunchang¹²³⁴^ORCID,Lee Dongwhan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Seoul National University

3. Seoul 08826

4. Korea

Abstract

Biomimetic cascade hydrogen bonds promote covalent capture of a nucleophile by polarizing the electrophilic reaction site, while suppressing non-productive acid–base chemistry as the competing reaction pathway.

Funder

National Research Foundation of Korea

Ministry of Science and ICT, South Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05067A

Reference50 articles.

1. Biomimetic carbohydrate recognition

2. Enantioselective carbohydrate recognition by synthetic lectins in water

3. Molecular Recognition of Hydrophilic Molecules in Water by Combining the Hydrophobic Effect with Hydrogen Bonding

4. Interfacial Supramolecular Structures of Amphiphilic Receptors Drive Aqueous Phosphate Recognition

5. Molecular recognition of pyrazine N,N′-dioxide using aryl extended calix[4]pyrroles

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