nBu4NI-Mediated oxidation of methyl ketones to α-ketoamides: using ammonium, primary and secondary amine-salt as an amine moiety-Reference-Cited by-同舟云学术

nBu4NI-Mediated oxidation of methyl ketones to α-ketoamides: using ammonium, primary and secondary amine-salt as an amine moiety

Published:2017 Issue:16 Volume:15 Page:3427-3434
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wang Dan¹²³⁴,Zhang Kuan¹²³⁴,Jia Luhan¹²³⁴,Zhang Danting¹²³⁴,Zhang Yue¹²³⁴,Cheng Yujia¹²³⁴,Lin Chang¹²³⁴,Wang Bo¹²³⁴⁵^ORCID

Affiliation:

1. State Key Lab of Marine Resource Utilisation in South China Sea

2. Hainan University

3. Haikou 570228

4. PR China

5. Institute of Chemical Engineering

Abstract

Presented is the first example of synthesizing an array of primary-, secondary-, and tertiary-α-ketoamides in moderate to excellent yields with a catalyst nBu₄NI from methyl ketones and amine/ammonium salts under mild conditions using oxidant TBHP.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00270J

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